Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjustedR2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2 -ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos.Secretaría de Estado de Investigación, Desarrollo e Innovación de España-AGL2015-69320-

Predicción de la frescura del aceite de oliva virgen extra durante el almacenamiento mediante espectroscopía de fluorescencia

Virgin olive oil quality relates to flavor and unique health benefits. Some of these properties are at the most desirable level when the oil is just extracted, since it is not a product that improves with age. On the contrary, the concentrations of many compounds change during its shelf-life. These changes reveal the aging of the oil but do not necessarily mean decay in sensory properties, so in some cases an aged oil from healthy olives may be better qualified than a fresh one from olives affected by fermentation. The aim of this work is to analyze different methodologies proposed for assessing the quality of virgin olive oil with implications in freshness and aging of the oil, and to highlight the possibilities of rapid spectrofluorimetric techniques for assessing oil freshness by checking the evolution of pigments during storage. The observed change in the selected spectral features and mathematical modelling over time was compared with the accepted model for predicting the amount of pyropheophytin a, which is based on isokinetic studies. The best regression was obtained for 655 nm (adjusted-R2 = 0.91) wavelength, which matches the distinctive band of pigments. The two mathematical models described in this study highlight the usefulness of pigments in the prediction of the shelf-life of extra virgin olive oil.La calidad del aceite de oliva virgen está relacionada con su flavor y sus beneficios únicos para la salud. Algunas de estas propiedades se encuentran en el nivel más deseable cuando el aceite está recién extraído, ya que no es un producto que mejore con el tiempo. Por el contrario, las concentraciones de muchos compuestos cambian a lo largo de la vida útil. Estos cambios revelan el envejecimiento del aceite, pero no implican necesariamente la alteración de las propiedades sensoriales, por lo que en algunos casos un aceite envejecido procedente de aceitunas sanas puede presentar mejor calidad que uno fresco procedente de aceitunas afectadas por procesos de fermentación. El objetivo de este trabajo es estudiar diferentes metodologías propuestas para evaluar la calidad del aceite de oliva virgen con implicaciones en la frescura y el envejecimiento del aceite, destacando las posibilidades de las rápidas técnicas espectrofluorométricas para evaluar la frescura del aceite verificando la evolución de los pigmentos durante el almacenamiento. El cambio observado en las características espectrales seleccionadas y su modelado matemático a lo largo del tiempo se comparó con el modelo aceptado para predecir la cantidad de pirofeofitina a, que se basa en estudios isocinéticos. Los dos modelos matemáticos descritos en este estudio pusieron de manifiesto la utilidad de los pigmentos en la predicción de la vida útil del aceite de oliva virgen extra. La mejor regresión se obtuvo para 655 nm (R2-ajustado = 0,91), longitud de onda que coincide con la banda distintiva de pigmentos

Routing Topologies of Wireless Sensor Networks for Health Monitoring of a Cultural Heritage Site

This paper provides a performance evaluation of tree and mesh routing topologies of wireless sensor networks (WSNs) in a cultural heritage site. The historical site selected was San Juan Bautista church in Talamanca de Jarama (Madrid, Spain). We report the preliminary analysis required to study the effects of heating in this historical location using WSNs to monitor the temperature and humidity conditions during periods of weeks. To test which routing topology was better for this kind of application, the WSNs were first deployed on the upper floor of the CAEND institute in Arganda del Rey simulating the church deployment, but in the former scenario there was no direct line of sight between the WSN elements. Two parameters were selected to evaluate the performance of the routing topologies of WSNs: the percentage of received messages and the lifetime of the wireless sensor network. To analyze in more detail which topology gave the best performance, other communication parameters were also measured. The tree topology used was the collection tree protocol and the mesh topology was the XMESH provided by MEMSIC (Andover, MA, USA). For the scenarios presented in this paper, it can be concluded that the tree topology lost fewer messages than the mesh topology.The Spanish Ministry of Economy and Competitiveness supported this research under grant numbers BIA2009-14395-C04-01 and TEC2012-38402-C04-03. The present study was also funded under project CGL2010-19554. S. Aparicio benefited from funding provided by the Spanish National Research Council (CSIC) through its Post-graduate Studies Council’s post-doctoral specialisation programme (JAE-Doc). Researcher Martínez-Garrido’s was supported by an International Programme for Recruiting Talent (PICATA) predoctoral fellowship awarded by the Moncloa Campus of International Excellence (UPM-UCM, CSIC). J. Ranz benefited from a FPI grant BES-2010-038826 of the Ministry of Education, Culture and Sports. We acknowledge support by the CSIC Open Access Publication Initiative through its Unit of Information Resources for Research (URICI

Crystallization and preliminary X-ray diffraction analysis of the N-terminal domain of Paenibacillus barcinonensis xylanase 10C containing the CBM22-1-CBM22-2 tandem

A construct containing the CBM22-1-CBM22-2 tandem forming the N-terminal domain of Paenibacillus barcinonensis xylanase 10C (Xyn10C) has been purified and crystallized. A xylan-binding function and an affinity for mixed [beta]-1,3/[beta]-1,4 glucans have previously been demonstrated for some members of the CBM22 family. The sequence of the tandem is homologous to the N-terminal domains found in several thermophilic enzymes. Crystals of this tandem were grown by the streak-seeding method after a long optimization strategy. The structure has been determined by molecular replacement to a resolution of 2.43 Å and refinement is under way. This study represents the first structure containing two contiguous CBM22 modules, which will contribute to a better understanding of the role that this multiplicity plays in fine-tuning substrate affinit

The ACS LCID project. VI. The SFH of the Tucana dSph and the relative ages of the isolated dSph galaxies

We present a detailed study of the star formation history (SFH) of the Tucana dwarf spheroidal galaxy. High quality, deep HST/ACS data, allowed us to obtain the deepest color-magnitude diagram to date, reaching the old main sequence turnoff (F814 ~ 29) with good photometric accuracy. Our analysis, based on three different SFH codes, shows that Tucana is an old and metal-poor stellar system, which experienced a strong initial burst of star formation at a very early epoch (~ 13 Gyr ago) which lasted a maximum of 1 Gyr (sigma value). We are not able to unambiguously answer the question of whether most star formation in Tucana occurred before or after the end of the reionization era, and we analyze alternative scenarios that may explain the transformation of Tucana from a gas-rich galaxy into a dSph. Current measurements of its radial velocity do not preclude that Tucana may have crossed the inner regions of the Local Group once, and so gas stripping by ram pressure and tides due to a close interaction cannot be ruled out. On the other hand, the high star formation rate measured at early times may have injected enough energy into the interstellar medium to blow out a significant fraction of the initial gas content. Gas that is heated but not blown out would also be more easily stripped via ram pressure. We compare the SFH inferred for Tucana with that of Cetus, the other isolated LG dSph galaxy in the LCID sample. We show that the formation time of the bulk of star formation in Cetus is clearly delayed with respect to that of Tucana. This reinforces the conclusion of Monelli et al. (2010) that Cetus formed the vast majority of its stars after the end of the reionization era implying, therefore, that small dwarf galaxies are not necessarily strongly affected by reionization, in agreement with many state-of-the-art cosmological models. [abridged]Comment: Accepted for publication on ApJ, 19 pages, 10 figures, 2 tables. A version with full resolution figures is available at http://www.iac.es/project/LCID/?p=publication

Larval fish assemblage structure in the surface layer of the northwestern Mediterranean under contrasting oceanographic scenarios

During the summer, the relative influence of resident Atlantic Waters (AW) and new AW largely drives the mesoscale dynamics around the Balearic Islands (NW Mediterranean). Two principal summer hydrographic scenarios were identified in the region, differentiated by the relative position of the density front between new and resident AW within the archipelago and its associated mesoscale activity. In this study, we investigated how those early summer mesoscale scenarios influence larval fish assemblages, by analyzing data from two cruises representative of these two scenarios (2004 and 2005). Redundancy analysis was used to assess the variance in the larval fish assemblage that could be significantly explained by the most parsimonious combination of available environmental variables in both years. While depth was the most important variable in explaining the larval fish assemblage structure variability observed under both scenarios, indicators of mesoscale activity (dynamic height, geostrophic velocity) contributed significantly to understanding the dynamics of the larval fish community. Mesoscale activity was higher in summer 2004, leading to higher larval fish abundances and zooplankton biomass and lower larval fish diversity than in the unusually warm summer 2005, which showed lower mesoscale activity. The larval assemblage dynamics are discussed in terms of extrinsic and species-specific factors.Postprint1,749

Stellar populations of galaxies in the ALHAMBRA survey up to z∼1z \sim 1. II. Stellar content of quiescent galaxies within the dust-corrected stellar mass−-colour and the UVJUVJ colour−-colour diagrams

Our aim is to determine the distribution of stellar population parameters (extinction, age, metallicity, and star formation rate) of quiescent galaxies within the rest-frame stellar mass$-$colour and $UVJ$ colour$-$colour diagrams corrected for extinction up to $z\sim1$. These novel diagrams reduce the contamination in samples of quiescent galaxies owing to dust-reddened galaxies, and they provide useful constraints on stellar population parameters. We set constraints on the stellar population parameters of quiescent galaxies combining the ALHAMBRA multi-filter photo-spectra with our SED-fitting code MUFFIT, making use of composite stellar population models. The extinction obtained by MUFFIT allowed us to remove dusty star-forming (DSF) galaxies from the sample of red $UVJ$ galaxies. The distributions of stellar population parameters across these rest-frame diagrams are revealed after the dust correction and are fitted by the LOESS method to reduce uncertainty effects. Quiescent galaxy samples defined via classical $UVJ$ diagrams are typically contaminated by a $\sim20$% fraction of DSF galaxies. A significant part of the galaxies in the green valley are actually obscured star-forming galaxies ($\sim30-65$%). Consequently, the transition of galaxies from the blue cloud to the red sequence, and hence the related mechanisms for quenching, seems to be much more efficient and faster than previously reported. The rest-frame stellar mass$-$colour and $UVJ$ colour$-$colour diagrams are useful for constraining the age, metallicity, extinction, and star formation rate of quiescent galaxies by only their redshift, rest-frame colours, and/or stellar mass. Dust correction plays an important role in understanding how quiescent galaxies are distributed in these diagrams and is key to performing a pure selection of quiescent galaxies via intrinsic colours.Comment: (37 pages, 29 figures, accepted for publication in A&A

GEOMETRIC DOCUMENTATION OF THE TORRE VALLFEROSA OF TORÀ

[EN] The Architecture and Archaeology depends on Geomatics to document Cultural Heritage in the best way, especially in the most complex situations or with those that present particular specifications. In this particular case, the Project of Torre de Vallferosa (Torà, Catalonia) has solved the way of representing indoor and outdoor tower’s Surface (cylindrical and conical shape). The solution provided to this is to develop and expand the surface through ad hoc software.[ES] Los campos de la Arquitectura y de la Arqueología necesitan de la Geomática para poder resolver la mejor forma de documentar el Patrimonio, sobre todo en los casos más complejos o que presenten unas características específicas o extraordinarias. En el presente trabajo presentamos el caso particular de la Torre Vallferosa (Torà, Catalunya), un proyecto donde se ha tenido que resolver la forma de representar la superficie de la torre, tanto la interior como la exterior, de aspecto cilíndrico y cónico, respectivamente. La solución adoptada ha sido la de desarrollar y desplegar la superficie mediante una aplicación realizada ad hoc para la ocasiónTortosa García, R.; Blasco I Senabre, J.; Aparicio González, Ó.; Gimeno Martínez, L.; Villaplana Sellés, A.; Menchón I Bes, J. (2016). DOCUMENTACIÓN GEOMÉTRICA DE LA TORRE VALLFEROSA DE TORÀ. En 8th International congress on archaeology, computer graphics, cultural heritage and innovation. Editorial Universitat Politècnica de València. 324-326. https://doi.org/10.4995/arqueologica8.2015.3546OCS32432